Six new poly(amide-imide)s (PAIs) 8a-f were synthesized from the direct polycondensation reaction of 1,1-bis[4-(trimellitimido)phenoxy]methane 6 with various aromatic diamine 7a–f. The polymerization reactions produced a series of thermally stable and organosoluble PAIs with high yield and good inherent viscosity. The resulted polymers were fully characterized by means of FTIR and ¹H-NMR spectroscopy, elemental analyses, inherent viscosity, and solubility tests. Also thermal properties of the PAIs 8a–f were investigated using thermal gravimetric analysis (TGA) and derivative of thermaogravimetric (DTG) analysis. dicarboxylic acid 6 was synthesized from the reaction of 1,1-bis[4-aminophenoxy]methane 4 with trimellitic anhydride 5 in a solution of glacial acetic acid/pyridine (Py) at refluxing temperature.

A new-type of dicarboxylic acid 6 was synthesized from the reaction of 1,4-bis[4-aminophenoxy]butane 4 with trimellitic anhydride 5 in a solution of glacial acetic acid/pyridine (Py) at refluxing temperature. 1,4-Bis[4-nitrophenoxy]butane 3 was prepared by reaction of 4-nitrophenol 1 with 1,4-dibromo butane 2 in N,N-dimethylformamide (DMF) solution. Then dinitro 3 was reduced to 1,4-bis[4-aminophenoxy]butane 4 by using 10% Pd–C, ethanol, and hydrazine monohydrate. So six new thermally stable and organosoluble poly(ether–ester–imide)s (PEEIs) 8a–f with good inherent viscosities were synthesized by the direct polycondensation reaction of new 1,4-bis[4-(trimellitimido)phenoxy]butane 6 with several aromatic diols 7a–f through direct polycondensation using tosyl chloride (TsCl)/pyridine (Py)/DMF system as condensing agent. The resulted polymers were fully characterized by means of FTIR and ¹H NMR spectroscopy, elemental analyses, inherent viscosity, solubility tests, differential scanning calorimeter (DSC), thermogravimetric analysis (TGA), and derivative of thermogravimetric (DTG).

New polyimide (PI) nanocomposites containing two different amounts of MWCNT (PI/MWCNT) were prepared via in situ polymerization technique. Transmission electron microscopy showed that MWCNT was exfoliated in the polymer matrix, resulting in well-dispersed morphologies at 1 and 3 mass% MWCNT contents. The effects of multiwalled carbon nanotubes (MWCNT) on the thermal and flammability properties of new PI derived from 1,3-bis[4,4′-aminophenoxy]propane and biphenyl dianhydride were investigated by thermogravimetric analysis (TG) in nitrogen and air atmosphere, differential scanning calorimetry, and microscale combustion calorimeter (MCC). The PI/MWCNT nanocomposites were electrically conductive with maximum conductivity obtained at 3 mass% MWCNT, which is favorable for many potential applications. TG results showed that the addition of MWCNT resulted in a substantial increase of the thermal stability and char yields of the nanocomposites compared to those of the neat PI. Flame retardancy of the nanocomposites was significantly improved in the presence of MWCNT.

Five new optically active polyamides (PAs) 6a–6e were prepared by direct polycondensation reaction of 2-(1,3-isoindolinedione-2-yl)-glutaric acid 4 as a new chiral diacid with various aromatic diamines 5a–5e in a medium consisting of triphenyl phosphite (TPP), calcium chloride, pyridine (Py) and N-methyl-2-pyrrolidone (NMP). The polycondensation reaction produced a series of polyamids 6a–6e in quantitative yields with inherent viscosities of 0.26–0.39 dL/g. The resulting polymers were fully characterized by means of 1H-NMR, FT-IR spectroscopy, elemental analysis, inherent viscosity and specific rotation. Thermal properties of these polymers were investigated using thermal gravimetric analysis (TGA) and differential thermal gravimetry (DTG). Phthalimide rings as a bulky pendent group in the polymer chains disturb the interchain and intrachain interactions and make these PAs readily soluble in polar, aprotic solvents such as N,N-dimethyl acetamide (DMAc), N,N-dimethyl formamide (DMF), dimethyl sulfoxide (DMSO), N-methyl-2-pyrrolidone (NMP) and sulfuric acid.

In this study a new series of magnetic and heat resistant nanocomposites were prepared based on a highly soluble poly(imide-ether) (PIE) reinforced with two different types of magnetic nanoparticles via a solution intercalation technique. New PIE with good solubility and desired molar mass containing bulky xanthene rings and amide groups in the side chains was synthesized via thermal cyclization of the poly(amic acid) precursor, obtained from the reaction of a new diamine derived from 9H-xanthene and 4,4′-oxydiphthalic dianhydride (ODPA). Improved solubility was attributed to the presence of xanthene group and flexible ether linkage in the polyimide backbones that reduce the chain-chain interaction and enhance solubility by penetrating solvent molecules into the polyimide chains. Fe₃O₄ nanoparticles (MNPs) which synthesized from chemical co-precipitation route were coated with silica (SiO₂), sequentially with (3-aminopropyl)triethoxysilane and poly-melamine-terephthaldehyde (MNPs-PMT), and then separately dispersed in the poly(amic acid) solutions and thermally imidized to form PIE/Fe₃O₄ and PIE/MNPs-PMT nanocomposites. The nanostructures and properties of the resultant materials were investigated using FTIR spectroscopy, X-ray diffraction (XRD), field emission scanning electron microscopy (FE-SEM), transmission electron microscopy (TEM), vibrating sample magnetometer (VSM), thermal gravimetric analysis (TGA) and differential scanning calorimetry (DSC). The properties of the nanocomposites were strongly related to the dispersion and interaction between the nanoparticles and PIE matrix. The thermogravimetric analysis (TGA) results showed that the addition of MNPs-PMT nanoparticles resulted in a substantial increase in the thermal stability of the corresponding PIEN. The temperature at 10% weight loss (T₁₀) was increased from 416 °C to 428 °C for PIEN containing 3 wt% MNPs-PMT as compared to neat PIE, as well the char yield enhanced. Furthermore, the MNPs-PMT nanoparticles had better dispersion in the polymer matrix due to the strong intermolecular hydrogen bond interactions between the NH and C=N groups of surface-modified nanoparticles and the PIE matrix than the uncoated Fe₃O₄ nanoparticles, and exhibited a better intercalated morphology and improved thermal properties. Also, the PIEN nanocomposites under applied magnetic field exhibited the hysteretic loops of the superparamagnetic nature.

Six new photosensitive and optically active poly(amide-imide)s 8a–8f with good inherent viscosities based on dibenzalacetone moiety were synthesized from the direct polycondensation reaction of N-Trimellitylimido-L-amino acids 3a–3f with 2,5-bis(4-aminobenzylidene)cyclopentanone 7 by two different methods such as direct polycondensation in a medium consisting of N-methyl-2-pyrrolidone/triphenyl phosphite/calcium chloride/pyridine and direct polycondensation in a tosyl chloride/pyridine (py)/N,N-dimethylformamide system. Diamine 7 was synthesized by using a two-step reaction. At first 2,5-bis(4-nitrobenzylidene)cyclopentanone 6 was prepared from the reaction of two equimolars 4-nitrobenzaldehyde 5 and one equimolar cyclopentanone 4 and dinitro compound 6 was reduced by using Na2S. Also N-trimellitylimido-L-amino acids 3a–3f were synthesized by the condensation reaction of trimellitic anhydride 1 with two equimolars of various L-amino acids 2a–2f in an acetic acid solution. The polymerization reactions produced a series of photosensitive and optically active poly(amide-imide)s with high yield and good inherent viscosity. The resulted polymers were fully characterized by means of FTIR and ¹H-NMR spectroscopy, elemental analyses, inherent viscosity, specific rotation, solubility tests, UV-VIS spectroscopy, differential scanning calorimeter, thermogravimetric analysis, and derivative of thermogravimetric. These macromolecules exhibited maximum UV-VIS absorption at around 395 and 265 nm in a N,N-dimethylformamide solution.

New type of nanocomposite materials were produced using a poly(amide-imide) (PAI) matrix and novel organoclay as a reinforcing agent by solution intercalation technique in N-methyl-2-pyrrolidone (NMP). The organoclay was prepared from Cloisite Na⁺ and protonated form of bis(3-amino phenyl)phenyl phosphine oxide via ion-exchange reaction. It was confirmed by Fourier transform infrared spectroscopy and X-ray powder diffraction techniques. A new PAI containing phenylacetic acid moiety was synthesized by direct polycondensation reaction of 2,2′-(5,5′-oxybis(1,3-dioxoisoindoline-5,2-diyl))bis(2-phenylacetic acid) as a new diacid and 4,4′-diaminodiphenylsulfone. Poly(amide-imide)/nanocomposites (PAIN)s containing 4 and 8 % of new organoclay were prepared via solution intercalation method through blending of organoclay with the PAI solution. The nanostructures and properties of the PAINs were investigated using different techniques. Transmission electron microscopy and XRD results revealed the good dispersion nano silicate layers in the polymer matrix. Thermal properties and flame retardancy of the resulting PAINs were investigated by thermal gravimetry analyses and microscale combustion calorimetry techniques. Organoclay shows a good effect on improving the flame retardancy of the PAI, reflecting the decrease in heat release rate (HRR) from 250 W/g for PAI to 185 and 157 W/g for PAINs, while the thermal stability of the PAI nanocomposites only increased slightly compared to the neat polymer.

A new series of aromatic poly(ester-imide)s (PEIs) 8a–f with 1,3-bis[4-aminophenoxy]propane moieties were prepared from the newly synthesized diacid monomer 6 with various aromatic diols 7a–f. The resulting polymers were fully characterized by Fourier transform infrared spectroscopy (FTIR) and ¹H nuclear magnetic resonance spectroscopy (¹H NMR), elemental analysis, inherent viscosity, solubility tests, thermogravimetric analysis (TGA), and derivative of thermogravimetric (DTG) analysis. The PEIs had inherent viscosity ranging from 0.18 to 0.90 dL/g and were soluble in common organic solvents, such as N,N-dimethylacetamide (DMAc), N-methyl-2-pyrrolidone (NMP), N,N-dimethylformamide (DMF), and dimethyl sulfoxide (DMSO). They exhibited useful thermal properties associated with relatively moderate T_gs (210–220 °C), 10% weight loss temperatures in excess of 380 °C, and char yields at 800 °C in N₂ of up to 29%. Dicarboxylic acid 6 was synthesized from the reaction of 1,3-bis[3-aminophenoxy] propane 4 with trimellitic anhydride 5 in a solution of glacial acetic acid/pyridine (Py) at the refluxing temperature. 1,3-Bis[4-nitrophenoxy]propane 3 was prepared by a reaction of 4-nitrophenol 1 with 1,3-dibromo propane 2 in a DMF solution. Dinitro 3 was reduced to diamine 4 using 10% Pd-C, ethanol and hydrazine monohydrate.

New optically active poly(ester-imide)s PEIs were prepared from newly synthesized N,N′-(bicyclo[2,2,2]oct-7-ene-2,3,5,6-tetracarboxylic)-bis-l-isoleucine diacid 4 via direct polycondensation with various aromatic diols in a system of tosyl chloride (TsCl), pyridine (Py), and N,N-dimethylformamide (DMF). The reactions with bicyclo TsCl were significantly promoted by controlling alcoholysis with diols, in the presence of catalytic amounts of DMF, to give a series of optically active PEIs, with good yield and moderate inherent viscosity ranging from 0.44 to 0.66 dL/g. The diacid 4 was synthesized by the condensation reaction of [2,2,2]oct-7-ene-2,3,5,6-tetracarboxylic dianhydride 1 with l-isoleucine 2 in acetic acid. All of these polymers were highly organosoluble in solvents such as N,N-dimethylacetamide (DMAc), N,N-dimethylformamide (DMF), dimethylsulfoxide (DMSO), and N-methyl-2-pyrrolidone (NMP) at room temperature. They were fully characterized by means of NMR spectroscopy, FTIR spectroscopy, gel permeation chromatography (GPC), elemental analyses, inherent viscosity, solubility test, and specific rotation, and thermal properties of the poly(ester-imide)s were investigated using TGA/DTG.

Semi-aromatic flame retardant polyether-amide/organoclay nanocomposites were synthesis through solution blending technique. Surface modification of the montmorillonite clay was performed with 1,4-bis[4,4′-amino phenoxy]butane for ample compatibilization with the polyamide matrix. The polymer chains were produced from the poly condensation reaction of bis(3-amino phenyl)phenyl phosphine oxide (4) with 1,4-(4-carboxy phenoxy)butane (3). The effect of clay dispersion and the interaction between clay and polyamide chains on the properties of nanocomposites were investigated using X-ray diffraction, scanning electron microscopy, limited oxygen index, differential scanning calorimetry, thermogravimetric analysis, and water uptake measurements. The diacid 3 as a monomer was prepared from the reaction of 4-hydroxy benzoic acid (1) with 1,4-dibromo butane (2) in the presence of NaOH solution.